LED

Electroluminescence was discovered in 1907 by the British experimenter H. J. Round of Marconi Labs, using a crystal of silicon carbide and a cat's-whisker detector. Russian Oleg Vladimirovich Losev independently created the first LED in the mid 1920s; his research, was distributed in Russian, German and British scientific journals, but no practical use was made of the discovery for several decades. Rubin Braunstein of the Radio Corporation of America reported on infrared emission from gallium arsenide (GaAs) and other semiconductor alloys in 1955. Braunstein observed infrared emission generated by simple diode structures using gallium antimonide (GaSb), GaAs, indium phosphide (InP), and silicon-germanium (SiGe) alloys at room temperature and at 77 kelvin.

In 1961, experimenters Bob Biard and Gary Pittman working at Texas Instruments, found that GaAs emitted infrared radiation when electric current was applied and received the patent for the infrared LED.

The first practical visible-spectrum (red) LED was developed in 1962 by Nick Holonya Jr., while working at General Electric Company. Holonyak is seen as the "father of the light-emitting diode". M. George Craford, a former graduate student of Holonyak, invented the first yellow LED and improved the brightness of red and red-orange LEDs by a factor of ten in 1972. In 1976, T.P. Pearsall created the first high-brightness, high efficiency LEDs for optical fiber telecommunications by inventing new semiconductor materials specifically adapted to optical fiber transmission wavelengths.

Up to 1968 visible and infrared LEDs were extremely costly, on the order of US $200 per unit, and so had little practical application. The Monsanto Corporation was the first organization to mass-produce visible LEDs, using gallium arsenide phosphide in 1968 to produce red LEDs suitable for indicators. Hewlett Packard (HP) introduced LEDs in 1968, initially using GaAsP supplied by Monsanto. The technology proved to have major applications for alphanumeric displays and was integrated into HP's early handheld calculators.

Efficiency and operational parameters

Typical indicator LEDs are designed to operate with no more than 30–60 milliwatts [mW] of electrical power. Around 1999, Philips Lumileds introduced power LEDs capable of continuous use at one watt [W]. These LEDs used much larger semiconductor die sizes to handle the large power inputs. Also, the semiconductor dies were mounted onto metal slugs to allow for heat removal from the LED die.

One of the key advantages of LED-based lighting is its high efficiency, as measured by its light output per unit power input. White LEDs quickly matched and overtook the efficiency of standard incandescent lighting systems. In 2002, Lumileds made five-watt LEDs available with a luminous efficiency of 18–22 lumens per watt [lm/W]. For comparison, a conventional 60–100 W incandescent lightbulb produces around 15 lm/W, and standard fluorescent lights produce up to 100 lm/W. (The luminous efficiency article discusses these comparisons in more detail.)

In September 2003, a new type of blue LED was demonstrated by the company Cree, Inc. to provide 24 mW at 20 milliamperes [mA]. This produced a commercially packaged white light giving 65 lm/W at 20 mA, becoming the brightest white LED commercially available at the time, and more than four times as efficient as standard incandescent. In 2006 they demonstrated a prototype with a record white LED luminous efficiency of 131 lm/W at 20 mA. Also, Seoul Semiconductor has plans for 135 lm/W by 2007 and 145 lm/W by 2008, which would be approaching an order of magnitude improvement over standard incandescents and better even than standard fluorescents. Nichia Corporation has developed a white light LED with luminous efficiency of 150 lm/W at a forward current of 20 mA.

It should be noted that high-power (≥ 1 W) LEDs are necessary for practical general lighting applications. Typical operating currents for these devices begin at 350 mA. The highest efficiency high-power white LED is claimed by Philips Lumileds Lighting Co. with a luminous efficiency of 115 lm/W (350 mA).

Cree issued a press release on November 19, 2008 about a laboratory prototype LED achieving 161 lumens/watt at room temperature. The total output was 173 lumens, and the correlated color temperature was reported to be 4689 K.

Life time and failure

Solid state devices such as LEDs are subject to very limited wear and tear if operated at low currents and at low temperatures. Many of the LEDs produced in the 1970s and 1980s are still in service today. Typical lifetimes quoted are 25000 to 100000 hours but heat and current settings can extend or shorten this time significantly.

The most common way for LEDs (and diode lasers) to fail is the gradual lowering of light output and loss of efficiency. Sudden failures, however rare, can occur as well. Early red LEDs were notable for their short lifetime. With the the development of high power LEDs the devices are subjected to higher junction temperatures and higher current densities than traditional devices. This causes stress on the material and may cause early light output degradation. To quantitatively classify lifetime in a standardized manner it has been suggested to use the terms L75 and L50 which is the time it will take a given LED to reach 75% and 50% light output respectively.

British experimenter H. J. Round

Dr. Robert Biard and Dr. Gary Pittman Texas Instruments experimenters in 1961

Nick Holonya Jr., General Electric Company